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Complexation with pagoda[ n ]arene ( n = 4, 5) protects ferrocenium from oxidation.

Gui-Hua ChenYi-Meng DuanYing LiXiao-Ni HanKun-Peng WangZhi-Qiang HuChuan-Feng Chen
Published in: Chemical communications (Cambridge, England) (2023)
The complexation behaviors of pagoda[ n ]arenes ( n = 4, 5) with ferrocene, ferrocenium and analogues cobaltocenium were studied. The inclusion complexes of pagoda[ n ]arenes can protect ferrocenium from oxidation in organic solvents and improve the stability and oxygen resistance of ferrocenium.
Keyphrases
  • hydrogen peroxide
  • water soluble
  • molecular docking
  • ionic liquid
  • electron transfer
  • structure activity relationship
  • nitric oxide