Isolation and Reactivity of an Antiaromatic s-Block Metal Compound.
Dipak Kumar RoyTobias TrösterFelipe FantuzziRian D DewhurstCarsten LenczykKrzysztof RadackiConor PranckeviciusBernd EngelsHolger BraunschweigPublished in: Angewandte Chemie (International ed. in English) (2020)
The concepts of aromaticity and antiaromaticity have a long history, and countless demonstrations of these phenomena have been made with molecules based on elements from the p, d, and f blocks of the periodic table. In contrast, the limited oxidation-state flexibility of the s-block metals has long stood in the way of their participation in sophisticated π-bonding arrangements, and truly antiaromatic systems containing s-block metals are altogether absent or remain poorly defined. Using spectroscopic, structural, and computational techniques, we present herein the synthesis and authentication of a heterocyclic compound containing the alkaline earth metal beryllium that exhibits significant antiaromaticity, and detail its chemical reduction and Lewis-base-coordination chemistry.