MXene-Based Micro-Supercapacitors: Ink Rheology, Microelectrode Design and Integrated System.

MXenes have shown great potential for micro-supercapacitors (MSCs) due to the high metallic conductivity, tunable interlayer spacing and intercalation pseudocapacitance. In particular, the negative surface charge and high hydrophilicity of MXenes make them suitable for various solution processing strategies. Nevertheless, a comprehensive review of solution processing of MXene MSCs has not been conducted. In this review, we present a comprehensive summary of the state-of-the-art of MXene MSCs in terms of ink rheology, microelectrode design and integrated system. The ink formulation and rheological behavior of MXenes for different solution processing strategies, which are essential for high quality printed/coated films, are presented. The effects of MXene and its compounds, 3D electrode structure, and asymmetric design on the electrochemical properties of MXene MSCs are discussed in detail. Equally important, we summarize the integrated system and intelligent applications of MXene MSCs and present the current challenges and prospects for the development of high-performance MXene MSCs.