π Complexes of P^P and P^N chelated gold(i).

Miquel NavarroAlberto ToledoMaximilian JoostAbderrahmane AmgouneSonia Mallet-LadeiraDidier Bourissou

Published in: Chemical communications (Cambridge, England) (2019)

Tricoordinate gold(i) π-complexes containing P-based chelating ligands (P^P and P^N) were prepared. The structure of the gold(i) styrene complexes has been analysed in detail based on NMR and XRD data. The P^N complex is a competent catalyst for indole alkylation. The reaction proceeds with complete C3 and Markovnikov selectivity.

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