Immobilization of the Polar Group into an Ultramicroporous Metal-Organic Framework Enabling Benchmark Inverse Selective CO 2 /C 2 H 2 Separation with Record C 2 H 2 Production.

One-step harvest of high-purity light hydrocarbons without the desorption process represents an advanced and highly efficient strategy for the purification of target substances. The separation and purification of acetylene (C 2 H 2 ) from carbon dioxide (CO 2 ) by CO 2 -selective adsorbents are urgently demanded yet are very challenging owing to their similar physicochemical properties. Here, we employ the pore chemistry strategy to adjust the pore environment by immobilizing polar groups into an ultramicroporous metal-organic framework (MOF), achieving one-step manufacture of high-purity C 2 H 2 from CO 2 /C 2 H 2 mixtures. Embedding methyl groups into prototype stable MOF (Zn-ox-trz) not only changes the pore environment but also improves the discrimination of guest molecules. The methyl-functionalized Zn-ox-mtz thus exhibits the benchmark reverse CO 2 /C 2 H 2 uptake ratio of 12.6 (123.32/9.79 cm 3 cm -3 ) and an exceptionally high equimolar CO 2 /C 2 H 2 selectivity of 1064.9 at ambient conditions. Molecular simulations reveal that the synergetic effect of pore confinement and surfaces decorated with methyl groups provides high recognition of CO 2 molecules through multiple van der Waals interactions. The column breakthrough experiments suggest that Zn - ox - mtz dramatically achieved the one-step purification capacity of C 2 H 2 from the CO 2 /C 2 H 2 mixture with a record C 2 H 2 productivity of 2091 mmol kg -1 , surpassing all of the CO 2 -selective adsorbents reported so far. In addition, Zn - ox - mtz exhibits excellent chemical stability under different pH values of aqueous solutions (pH = 1-12). Moreover, the highly stable framework and excellent inverse selective CO 2 /C 2 H 2 separation performance showcase its promising application as a C 2 H 2 splitter for industrial manufacture. This work paves the way to developing reverse-selective adsorbents for the challenging gas separation process.