Polyoxometalates Templated Metal Ag-Carbene Frameworks Anodic Material for Lithium-Ion Batteries.

A POMs templated 3D Ag-carbene framework with lvt-a topology was hydrothermally synthesized. The POMs templated MCF combining the advantages of POMs, MOFs, and carbene not only shows excellent thermal and chemical stabilities but also possesses a good discharge capacity of 481 mAh·g-1 after 100 cycles applied as anode material in LIBs.