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(E)-2-(2-Hy-droxy-3-methyl-benzyl-idene)-N-methyl-hydrazine-1-carbo-thio-amide: supra-molecular assemblies in two-dimensions mediated by N-H⋯S and C-H⋯π inter-actions.

Md Azharul ArafathHuey Chong KwongFarook Adam
Published in: Acta crystallographica. Section E, Crystallographic communications (2019)
In the title compound, C10H13N3OS, the azomethine C=N double bond has an E configuration. The phenyl ring and methyl-hydrazine carbo-thio-amide moiety [maximum deviation = 0.008 (2) Å] are twisted slightly with a dihedral angle of 14.88 (10)°. In the crystal, mol-ecules are linked into sheets parallel to the ab plane via N-H⋯S hydrogen bonds and C-H⋯π inter-actions.
Keyphrases
  • fluorescent probe
  • high resolution
  • transition metal
  • single molecule