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Identification of new trace related impurities in adenosine products using ultra-high-performance liquid chromatography/electrospray ionization quadrupole time-of-flight tandem mass spectrometry.

Yeming ShenPeilu ZhaiPengxuan XiChen ChenFangjing MouFuxin LiJianye Zhang
Published in: Rapid communications in mass spectrometry : RCM (2020)
A UHPLC/QTOF-MS method was established and used for the separation and characterization of nine trace related impurities of adenosine. Their structures were identified based on the MS and MS/MS spectra and retention times. In addition, the specific MS/MS fingerprints of the monosaccharide glycosyl moieties of the adenosine impurity analogs were summarized.
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