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Two and three-dimensional halogen-bonded frameworks: self-assembly influenced by crystallization solvents.

Chuan-Zhi LiuJing-Jing WangBo YangZhong-Yi LiMeng YanXin-Ming LiuZhi-Yuan HuLan-Tao LiuZhan-Ting Li
Published in: Chemical communications (Cambridge, England) (2023)
In this paper, two types of solid phase 2D and 3D XBOFs were selectively constructed from identical building blocks of tetraphenylmethane tetrapyridine derivative and 1,4-diiodotetrafluorobenzene by changing the crystallization solvent. This 3D XBOF is a novel hybrid supramolecular organic framework with the synergistic control of hydrogen and halogen bonds.
Keyphrases
  • water soluble
  • ionic liquid
  • wastewater treatment
  • cancer therapy
  • drug delivery
  • solar cells