Assembly of Metal-Organic Frameworks of SiF62- in Situ Formed from Borosilicate Glass.
Meng-Ying SunXue-Zhi WangZi-Ye ChenXiao-Ping ZhouDan LiPublished in: Inorganic chemistry (2019)
The SiF62- anions are in situ formed in the reactions of MF2 (M = Cu2+, Zn2+, Ni2+, and Co2+) salts and nitrogen-containing ligands in borosilicate glass tubes under solvothermal conditions and then used to further construct a family of metal-organic frameworks (MOFs). This in situ reaction demonstrates a new and facile strategy for the fabrication of MOFs based on SiF62-.