An Emerging Chemistry Revives Proton Batteries.

Developing new energy techniques that simultaneously integrate the fast rate capabilities of supercapacitors and high capacities of batteries represents an ultimate goal in the field of electrochemical energy storage. A new possibility arises with an emerging battery chemistry that relies on proton-ions as the ion-charge-carrier and benefits from the fast transportation kinetics. Proton-based battery chemistry starts with the recent discoveries of materials for proton redox reactions and leads to a renaissance of proton batteries. In this article, the historical developments of proton batteries are outlined and key aspects of battery chemistry are reviewed. First, the fundamental knowledge of proton-ions and their transportation characteristics is introduced; second, Faradaic electrodes for proton storage are categorized and highlighted in detail; then, reported electrolytes and different designs of proton batteries are summarized; last, perspectives of developments for proton batteries are proposed. It is hoped that this review will provide guidance on the rational designs of proton batteries and benefit future developments.