Luminescence Enhancement of CsMnBr 3 Nanocrystals through Heterometallic Doping.

The absorption and photoluminescence (PL) of CsMnBr 3 with Mn(II) in octahedral crystal fields are extremely weak due to a d-d forbidden transition. Herein, we introduce a facile and general synthetic procedure that can prepare undoped and heterometallic doped CsMnBr 3 NCs at room temperature. Importantly, both PL and absorption of CsMnBr 3 NCs were significantly improved after doping a small amount of Pb 2+ (4.9%). The absolute photoluminescence quantum yield (PL QY) of Pb-doped CsMnBr 3 NCs is up to 41.5%, 11-fold higher than undoped CsMnBr 3 NCs (3.7%). The PL enhancement is attributed to the synergistic effects between [MnBr 6 ] 4- units and [PbBr 6 ] 4- units. Furthermore, we verified the similar synergistic effects between [MnBr 6 ] 4- units and [SbBr 6 ] 4- units in Sb-doped CsMnBr 3 NCs. Our results highlight the potential of tailoring luminescence properties of manganese halides through heterometallic doping.