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Copper catalysed protoboration of allenyl-Bdans: efficient synthesis of β-boryl allyl-Bdans.

Shi-Sen LiQin ZhongJian Ken Zhao
Published in: Organic & biomolecular chemistry (2022)
An efficient Cu-catalysed protoboration of allenyl-Bdans is presented. Under the optimized reaction conditions, a series of allenyl-Bdans reacted smoothly with B<sub>2</sub>Pin<sub>2</sub> to afford β-boryl allyl-Bdans in moderate to high yields with excellent regio- and stereoselectivity.
Keyphrases
  • high intensity