Login / Signup

Transition Metal Ions in Methylammonium Chloride Perovskites.

Chih-Shan Tan
Published in: ACS omega (2021)
Organic-inorganic perovskite materials have become star materials for future wide band gap optoelectronics due to their excellent optical and electrical properties. However, the lead ions inside perovskites have become a crucial environmental issue in the commercialization of wide band gap perovskite devices . This research tries to find the structure and properties of lead-free perovskite materials by screening Sn 2+ and transition-metal ions to replace Pb 2+ within the methylammonium (MA)-based chloride perovskite and find out a new two-dimensional structure of MA-based transition-metal ion chlorides. Overall, MAZnCl 3 may be a potential ultraviolet-C luminescent material with a stable two-dimensional structure with a wide band gap of 5.64 eV, which is suitable for ultraviolet-C luminescence applications.
Keyphrases
  • transition metal
  • solar cells
  • quantum dots
  • room temperature
  • high efficiency
  • water soluble
  • aqueous solution
  • sensitive detection
  • human health
  • energy transfer
  • heavy metals
  • high resolution
  • high speed
  • climate change