Development and Digital Light Processing 3D Printing of a Vitrimer Composed of Glycerol 1,3-Diglycerolate Diacrylate and Tetrahydrofurfuryl Methacrylate.

The development of biobased reshapable and repairable vitrimers has received extensive attention due to the growing focus on an environmentally friendly society. Therefore, the objective of this research was to synthesize sustainable polymers with an environmentally friendly strategy combining the benefits of renewable resources, UV curing, and vitrimers. Two biobased monomers, glycerol 1,3-diglycerolate diacrylate and tetrahydrofurfuryl methacrylate, were chosen for the preparation of UV-curable resins and tested by real-time photorheometry and RT-FTIR spectroscopy to determine their suitability for digital light processing (DLP) 3D printing. DLP 3D-printed polymer showed shape memory, weldability, and repairability capabilities by triggering the dynamic transesterification process at high temperatures. The vitrimer with a weight ratio of 60:40 of glycerol 1,3-diglycerolate diacrylate and tetrahydrofurfuryl methacrylate showed shape memory properties with a recovery ratio of 100% and a 7-fold improved tensile strength compared to the original sample, confirming efficient weldability and repairability.