Planar Pentacoordinate Nitrogen in a Pseudo-Double-Aromatic NBe5H4+ Cluster.
Amlan J KalitaShahnaz S RohmanChayanika KashyapSabnam S UllahIndrani BaruahAnkur Kanti GuhaPublished in: Inorganic chemistry (2020)
High-level quantum-chemical calculations have been used to predict a cationic ternary NBe5H4+ cluster containing a planar pentacoordinate nitrogen atom. The proposed cluster has pseudo dual aromaticity and is kinetically and thermodynamically very stable.