Facile synthesis of a semiconducting bithiophene-azine polymer and its application for organic thin film transistors and organic photovoltaics.

A new azine polymer poly(4,4'-didodecyl-2,2'-bithiophene-azine) (PDDBTA) was synthesized in only three steps. PDDBTA showed hole mobilities of up to 4.1 × 10 -2 cm 2 V -1 s -1 in organic thin film transistors (OTFTs) as a p-channel material. As a donor in organic photovoltaics (OPVs), power conversion efficiencies (PCEs) of up to 2.18% were achieved, which is the first example of using an azine-based polymer for OPVs. These preliminary results demonstrate the potential of bithiophene-azine polymers as a new type of low-cost semiconductor material for OPVs and other organic electronics.