Chemoselective hydrogenation of heteroarenes and arenes by Pd-Ru-PVP under mild conditions.

Chandan ChaudhariKatsutoshi SatoYoshihide NishidaTomokazu YamamotoTakaaki ToriyamaSyo MatsumuraYasuyuki IkedaKenji TeradaNaoya AbeKohei Kusuda Hiroshi Kitagawa Katsutoshi Nagaoka

Published in: RSC advances (2020)

Monometallic (Pd, Ru or Rh) and bimetallic (Pd 0.5 -Ru 0.5 ) alloy NPs catalysts were examined for the hydrogenation of quinoline. Pd-Ru alloy catalyst showed superior catalytic activity to the traditional Rh catalyst. The characterization of Pd 0.5 -Ru 0.5 catalysts, HAADF-EDX mapping and XPS analysis suggested that the alloy state of PdRu catalysts remained unchanged in the recovered catalyst. Furthermore, the catalyst was highly selective for the hydrogenation of different arenes.

Keyphrases

highly efficient
metal organic framework
room temperature
ionic liquid
energy transfer
reduced graphene oxide
carbon dioxide
visible light
high resolution
gold nanoparticles
molecular docking
high density
molecular dynamics simulations
data analysis