With the acceleration of informatization and the coverage of wireless networks, homes, conferences, schools and other places have a higher pursuit of the wireless transmission capabilities of electronic devices. Wireless screen transmission technology is used more frequently in life, work and study. This article mainly discusses the practical application of network multimedia courseware in college basketball teaching. This article first elaborates the teaching plan of multimedia courseware, including teaching content, teacher guidance, student learning and multimedia courseware. Secondly, the multimedia courseware of basketball tactics basic teaching is completed by using Flash mx2004 plug-in. After that, it specifically introduces the process of how to transmit basketball teaching content through multimedia equipment to the video network for students to learn under the wireless network environment. It emphasizes that the "wireless multimedia communication" course is an important course in the electronic information subject. Finally, through the teaching experiment, the accuracy of the multimedia teaching method was tested, and the validity of the courseware content was tested by the empirical validity evaluation method. At the same time, after the teaching experiment, in order to test the two groups of students' mastery of the basic coordination theory of basketball tactics, the basic coordination theory of basketball tactics was tested. The experimental group had 22 students with a score of 90 or more, accounting for 27.5%, and the control group had 13 students with a score of 90 or more, accounting for 16.5%. The results show that wireless network multimedia computer-assisted teaching has a positive effect on improving students' interest in learning.