Nickel-Catalyzed Isomerization of Homoallylic Alcohols.

Dustin D YoumansHai N TranLevi M Stanley

Published in: Organic letters (2023)

Nickel-catalyzed isomerizations of homoallylic alcohols and a bishomoallylic alcohol are presented. These isomerization reactions occur in the presence of a simple nickel catalyst that does not require addition of an exogenous ligand. The corresponding ketone products are generated in ≤98% yield.

Keyphrases

reduced graphene oxide
room temperature
metal organic framework
oxide nanoparticles
carbon nanotubes
gold nanoparticles
ionic liquid
highly efficient