Cucurbit[ n ]uril Supramolecular Assemblies-Regulated Charge Transfer for Luminescence Switching of Gold Nanoclusters.

Host-guest molecular assemblies are highly desirable for precisely controlling the luminescence properties of nanomaterials. Unfortunately, the design of high-quality luminescent nanoswitches is still very challenging due to the low affinity of traditional macrocyclic molecules (e.g., cyclodextrin) and inherently sophisticated electronic structures of nanoemitters. The current work represents the first to fabricate a luminescent nanoswitch using cucurbit[ n ]uril supramolecular assemblies-regulated luminescence of gold nanoclusters (AuNCs). It is found that, similar to a small-molecule fluorophore-based system, the luminescence of fabricated AuNC-cationic quencher nanohybrids can be reversibly manipulated by cucurbit[7]uril through altering the key parameters of the charge transfer process including the reorganization energy and electronic coupling between charge-transfer reactants. This study demonstrates the crucial role of cucurbit[ n ]uril host-guest assemblies in modulating the luminescence of AuNCs and their application in luminescence switching, thus offering new avenues for the fabrication and development of optical devices and smart materials.