Topotactic and Self-Templated Fabrication of Zn1-xCdxSe Porous Nanobelt-ZnO Nanorod for Photoelectrochemical Hydrogen Production.

Herein, we propose the topotactic and self-templated fabrication of Zn1-xCdxSe porous nanobelt-ZnO nanorod (termed as ZnCdSe/ZnO) photoelectrode via the cadmium (Cd2+) ion-exchange process on zinc (Zn) foil. Inorganic-organic hybrid ZnSe(en)0.5 nanobelt (NB) was synthesized on Zn foil by a facial solvothermal method at different temperatures of 140, 160, and 180 °C for 12 h. The interfacial properties and photoelectrochemical (PEC) performance of inorganic-organic ZnSe(en)0.5 NB fabricated through the Cd2+ ion-exchange method at different time durations of 6, 12, 18, and 24 h at 140 °C were investigated. The TEM analysis results indicate that the inorganic-organic ZnSe(en)0.5 NB transformed into ZnCdSe and a self-assembled ZnO formed on the Zn foil. In particular Cd2+ ion temperature (140 °C/18 h), the optimized ZnCdSe/ZnO-(F) photoelectrode shows an excellent photocurrent density of 14 mA·cm-2 at 0 V vs Ag/AgCl with 219 μmol·cm-2 hydrogen gas evolution for 3 h under 1 sun illumination. The higher photocurrent value resulted from the optimum growth of ZnO, the formation of porous ZnCdSe, and the effective electrolyte penetration for electron-hole pair separation. The photoluminescence spectroscopy shows that the photoexcited charged carriers promoted a longer lifetime. Furthermore, we provide a full account of the possible charge-transfer mechanism during PEC hydrogen production.