Macroscopic two-dimensional monolayer films of gold nanoparticles: fabrication strategies, surface engineering and functional applications.

In the last few decades, two-dimensional monolayer films of gold nanoparticles (2D MFGS) have attracted increasing attention in various fields, due to their superior attributes of macroscopic size and accessible fabrication, controllable electromagnetic enhancement, distinctive optical harvesting and electron transport capabilities. This review will focus on the recent progress of 2D monolayer films of gold nanoparticles in construction approaches, surface engineering strategies and functional applications in the optical and electric fields. The research challenges and prospective directions of 2D MFGS are also discussed. This review would promote a better understanding of 2D MFGS and establish a necessary bridge among the multidisciplinary research fields.