Stepwise construction of coordinative linkages and dynamic covalent linkages for a porous metal-organic framework.

Shuyin PengYuqian SunQingqing LiZhongwen JiangYin RaoYichen WuQiaowei Li

Published in: Chemical communications (Cambridge, England) (2024)

A cyclic trinuclear complex is synthesized from Ag I and 1 H -pyrazole-4-carbaldehyde. Reticulation of the complex with 1,3,5-tris(4-aminophenyl)benzene through Schiff-base reaction affords a porous FDM-72 framework. Amine choice is systematically investigated as it may initiate metal reduction. This study proposes a new route and its amine selection criterion to synthesize Ag-based frameworks.

Keyphrases

metal organic framework
quantum dots
highly efficient
molecular docking
atomic force microscopy
mass spectrometry
high resolution
decision making
oxide nanoparticles
high speed
electron transfer