BINOL blocks as accessible triplet state modulators in BODIPY dyes.

Josué JiménezRuth Prieto-MonteroSergio SerranoPatrycja StachelekEsther Rebollar Beatriz L Maroto Florencio Moreno Virginia Martínez-Martínez Robert PalInmaculada García-MorenoSantiago de la Moya

Published in: Chemical communications (Cambridge, England) (2022)

BINOL moieties of different electronic demand are useful blocks for enabling the photo-production and modulation of triplet excited states in readily-accesible BINOL-based O -BODIPY dyes from standard F -BODIPY precursors. The rapid and rational development of smarter triplet-enabling BODIPY dyes on the basis of this strategy ( e.g. , TADF biomarker 4a or room temperature phosphor 4g) paves the way for advancing photonic applications based on organic triplet photosensitizers.

Keyphrases

energy transfer
fluorescent probe
living cells
room temperature
quantum dots
aqueous solution
photodynamic therapy
small molecule
sensitive detection