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Pt-Free microengines at extremely low peroxide levels.

Heng YeGuofeng MaJian KangHongqi SunShaobin Wang
Published in: Chemical communications (Cambridge, England) (2018)
Herein, we demonstrate that iron oxide modified MnO2 (FeOx-MnO2) catalyzed micromotors can be fabricated via electrochemical co-reduction and exhibit exceptional high performance at an extremely low hydrogen peroxide (H2O2) fuel concentration. We observed that graphene/FeOx-MnO2 microtubes could show motion behaviors at fuel concentration as low as 0.03% H2O2, which is nearly one order of magnitude lower than Pt-based micromotors (normally at above 0.2% H2O2). Moreover, the micromotors exhibit higher speeds than any other reported catalytic micro/nanomotors (MNMs) at low peroxide levels. The FeOx-MnO2 systems are better catalytic MNMs, due to their excellent catalytic activity, easy fabrication, robust structure and movement, as well as low-cost, biocompatible and abundance nature, showing great potential for future applications.
Keyphrases
  • hydrogen peroxide
  • low cost
  • iron oxide
  • nitric oxide
  • room temperature
  • gold nanoparticles
  • drug delivery
  • high resolution