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New approaches to the functionalization of the 1-carba- closo -decaborate anion.

Akim V Shmal'koPaula CendoyaSergey A AnufrievKyrill Yu SuponitskyDetlef GabelIgor B Sivaev
Published in: Chemical communications (Cambridge, England) (2022)
Two new approaches to the functionalization of the 1-carba- closo -decaborate anion [1-CB 9 H 10 ] - at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and heteroaromatics were developed.
Keyphrases
  • ionic liquid
  • water soluble
  • amino acid