NHC-Coordinated Diphosphene-Stabilized Gold(I) Hydride and Its Reversible Conversion to Gold(I) Formate with CO2.

An NHC-coordinated diphosphene is employed as ligand for the synthesis of a hydrocarbon-soluble monomeric AuI hydride, which readily adds CO2 at room temperature yielding the corresponding AuI formate. The reversible reaction can be expedited by the addition of NHC, which induces β-hydride shift and the removal of CO2 from equilibrium through the formation of an NHC-CO2 adduct. The AuI formate is alternatively formed by dehydrogenative coupling of the AuI hydride with formic acid (HCO2 H), thus in total establishing a reaction sequence for the AuI hydride mediated dehydrogenation of HCO2 H as chemical hydrogen storage material.