Stress-Induced Shape-Shifting Materials Possessing Autonomous Self-Healing and Scratch-Resistant Ability.

Covalent adaptable networks (CANs) capable of both shape-shifting and self-healing ability offer a viable alternative to 4D printing technology to gain access to various complex shapes in a simplified manner. However, most of the reported CANs exhibit shape-shifting ability in the presence of temperature, light or chemical stimuli, which restricts their further utilization as realization of such a controlled environment is not feasible under complex scenarios. Herewith, we report a set of CANs based on a room-temperature exchangeable thia-Michael adduct, which undergoes rearrangement in network topology on application of external stress. These CANs with tensile strength (≤6 MPa) and modulus (≤71.4 MPa) adopt to any programmed shape under application of nominal stress. The CANs also exhibit stress-induced recyclability, self-welding and self-healing ability under ambient conditions. The transparency and ambient condition self-healing ability render these CANs to be utilized as scratch-resistant coatings on display items.