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A magnetic porous organic polymer: catalytic application in the synthesis of hybrid pyridines with indole, triazole and sulfonamide moieties.

Morteza TorabiMeysam YarieMohammad Ali ZolfigolSaeid AzizianYanlong Gu
Published in: RSC advances (2022)
Herein, the synthesis and characterization of a triazine-based magnetic ionic porous organic polymer are reported. The structure, morphology, and components of the prepared structure have been investigated with several spectroscopic and microscopic techniques such as FT-IR, EDX, elemental mapping, TGA/DTA, SEM, TEM, VSM, and BET analysis. Also, catalytic application of the prepared triazine-based magnetic ionic porous organic polymer was investigated for the synthesis of hybrid pyridine derivatives bearing indole, triazole and sulfonamide groups. Furthermore, the prepared hybrid pyridine systems were characterized by FT-IR, 1 H NMR, 13 C NMR and mass analysis. A cooperative vinylogous anomeric-based oxidation pathway was suggested for the synthesis of target molecules.
Keyphrases
  • high resolution
  • solid state
  • magnetic resonance
  • molecularly imprinted
  • metal organic framework
  • hydrogen peroxide
  • solid phase extraction
  • mass spectrometry
  • crystal structure
  • liquid chromatography