An investigation on the adsorption and removal performance of a carboxymethylcellulose-based 4-aminophenazone@MWCNT nanocomposite against crystal violet and brilliant green dyes.

The multistep chemical modification of carboxymethylcellulose (CMC) in the presence of 4-aminophenazone (A-PH) and multiwall carbon nanotubes (MWCNTs) has been successfully conducted. The environmental performance of this material has been thoroughly investigated. Crystal violet (CV) and brilliant green (BG) were eliminated by utilising a new hybrid nanocomposite material (A-PH-CMC/MWCNTs) from a simulated textile wastewater solution. Using SEM, EDX, XRD and FTIR spectroscopy methods, the detailed characterisation of A-PH-CMC/MWCNT nanocomposites was investigated. The results indicated that the adsorption capacity was dependent on six factors ( e.g. , contact duration, starting concentration, adsorbent mass, the effect of the solution pH, temperature and the effect of KNO 3 ). In addition, thermodynamic and regeneration studies have been reported. According to the theories of pseudo-second-order kinetics, the removal process involves chemical adsorption. The experimental results were best suited by the Langmuir model, in which maximum adsorption capacities of 20.83 and 22.42 mg g -1 were predicted for the BG and CV dyes, respectively. The research is a preliminary case study demonstrating the excellent potential of A-PH-CMC/MWCNT nanocomposites as a material for CV and BG dye removal.