A Strategy for Multigas Identification Using Multielectrical Parameters Extracted from a Single Carbon-Based Field-Effect Transistor Sensor.

Given the widespread utilization of gas sensors across various industries, the detection of diverse and complex target gases presents a significant challenge in designing sensors with multigas detection capability. Although constructing a sensor array with widely used chemiresistive gas sensors is one solution, it is difficult for a single chemiresistive gas sensor to simultaneously detect different gases, as it can only detect a single target gas. The intrinsic reason for this bottleneck is that chemiresistive gas sensors rely entirely on the resistivity as the unique parameter to evaluate the diverse gas sensing properties of sensors, such as sensitivity, selectivity, etc. Herein, a field-effect transistor (FET) with abundant electrical parameters is employed to prepare a gas sensor for the detection of a variety of gases. Semiconducting carbon nanotubes (CNTs) are selected as the channel material, which is modified by Pd nanoparticles to enhance the gas sensing properties of the sensors. By extracting various electrical parameters such as transconductance, threshold voltage, etc. from the transfer characteristic curves of FET, a correlation between multielectrical parameters and various gas detection information is established for subsequent data analysis. Through the utilization of the principal component analysis algorithm, the identification of six gases can be finally achieved by relying solely on a single carbon-based FET-type gas sensor. We hope our work can solve the bottleneck of multigas identification by a single sensor in principle and is expected to reduce the system complexity and cost caused by the design of sensor arrays, offering a valuable guidance for multigas identification technology.