Reduced electric field and gas temperature effects on chemical product dynamics in air surface dielectric barrier discharges: from macro-physical parameters to micro-chemical mechanisms.

To gain insights into the mechanisms of plasma chemical product interactions, the dynamic changes of the surface dielectric barrier discharge (SDBD) products are experimentally related to the reduced electric field and gas temperature. The higher applied voltage and frequency cause faster product changes from the O 3 -containing to the O 3 -free state, while raising the electron energy and gas temperature. The electron energy affects the electron collision reactions and the production of various reactive species, steering the chemical reactions towards the predominant production of NO over O 3 . The gas temperature affects the generation and quenching rates of the key products. Collectively, this work bridges macro-physical parameters and micro-chemical mechanisms through the electron energy and gas temperature effects, and contributes to better understanding of the physico-chemical processes in low-temperature plasmas.