Silver-Catalyzed N-H Functionalization of Aryl/Aryl Diazoalkanes with Anilines.
Feifei HeClaire EmpelRené M KoenigsPublished in: Organic letters (2021)
Herein, we report on the N-H functionalization reaction of primary and secondary anilines with diaryldiazoalkanes using simple AgPF6 as catalyst. We demonstrated broad applicability in the reaction of diaryldiazoalkanes with different anilines (31 examples, up to 97% yield). Furthermore, we propose a possible reaction mechanism for the N-H functionalization.