Isolation of uranium(III) primary phosphido complexes.

Diana PeralesRina BhowmickMatthias ZellerPere Miro Bess Vlaisavljevich Suzanne C Bart

Published in: Chemical communications (Cambridge, England) (2022)

Low-valent uranium(III) primary phosphido complexes supported by hydrotris(3,5-dimethylpyrazolyl)borate (Tp*) were synthesized with phosphines of varying steric and electronic profiles. Compounds were characterized by multinuclear NMR spectroscopy ( 1 H, 11 B, 31 P NMR), infrared spectroscopy, electronic absorption spectroscopy, X-ray crystallography, and quantum chemical calculations.

Keyphrases

high resolution
molecular dynamics
solid state
magnetic resonance
molecular dynamics simulations
mass spectrometry
computed tomography
contrast enhanced