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Do We Need "Ionosorbed" Oxygen Species? (Or, "A Surface Conductivity Model of Gas Sensitivity in Metal Oxides Based on Variable Surface Oxygen Vacancy Concentration").

Christopher S Blackman
Published in: ACS sensors (2021)
The author provides an opinion on direct experimental evidence available to support the "ionosorption theory" often employed to interpret "electrophysical" measurements made during a gas sensing experiment. This article then aims to provide an alternative framework of a "surface conductivity" model based on recent advances in theoretical and experimental investigations in solid state physics, and to use this framework as a guide toward design rules for future improvement of gas sensor performance.
Keyphrases
  • solid state
  • room temperature
  • carbon dioxide
  • ionic liquid