Login / Signup

Concentrated Nonaqueous Polyelectrolyte Solutions: High Na-Ion Transference Number and Surface-Tethered Polyanion Layer for Sodium-Metal Batteries.

Shinji KondouYusuke SakashitaAsuka MorinagaYu KatayamaKaoru DokkoMasayoshi WatanabeKazuhide Ueno
Published in: ACS applied materials & interfaces (2023)
Na metal is a promising anode material for the preparation of next-generation high-energy-density sodium-ion batteries; however, the high reactivity of Na metal severely limits the choice of electrolyte. In addition, rapid charge-discharge battery systems require electrolytes with high Na-ion transport properties. Herein, we demonstrate a stable and high-rate sodium-metal battery enabled by a nonaqueous polyelectrolyte solution composed of a weakly coordinating polyanion-type Na salt, poly[(4-styrenesulfonyl)-(trifluoromethanesulfonyl)imide] (poly(NaSTFSI)) copolymerized with butyl acrylate, in a propylene carbonate solution. It was found that this concentrated polyelectrolyte solution exhibited a remarkably high Na-ion transference number ( t Na PP = 0.9) and a high ionic conductivity (σ = 1.1 mS cm -1 ) at 60 °C. Furthermore, the surface of the Na electrode was modified with polyanion chains anchored via the partial decomposition of the electrolyte. The surface-tethered polyanion layer effectively suppressed the subsequent decomposition of the electrolyte, thereby enabling stable Na deposition/dissolution cycling. Finally, an assembled sodium-metal battery with a Na 0.44 MnO 2 cathode demonstrated an outstanding charge/discharge reversibility (Coulombic efficiency >99.8%) over 200 cycles while also exhibiting a high discharge rate (i.e., 45% capacity retention at 10 mA cm -2 ).
Keyphrases
  • ion batteries
  • solid state
  • ionic liquid
  • multiple sclerosis
  • mass spectrometry
  • high resolution
  • ms ms
  • gold nanoparticles
  • simultaneous determination
  • capillary electrophoresis