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Possible enhancement of the superconductingTcdue to sharp Kohn-like soft phonon anomalies.

Cunyuan JiangEnrico BeneduceMatteo BaggioliChandan SettyAlessio Zaccone
Published in: Journal of physics. Condensed matter : an Institute of Physics journal (2023)
Phonon softening is a ubiquitous phenomenon in condensed matter systems which is often associated with charge density wave (CDW) instabilities and anharmonicity. The interplay between phonon softening, CDW and superconductivity is a topic of intense debate. In this work, the effects of anomalous soft phonon instabilities on superconductivity are studied based on a recently developed theoretical framework that accounts for phonon damping and softening within the Migdal-Eliashberg theory. Model calculations show that the phonon softening in the form of a sharp dip in the phonon dispersion relation, either acoustic or optical (including the case of Kohn-type anomalies typically associated with CDW), can cause a manifold increase of the electron-phonon coupling constant λ . This, under certain conditions, which are consistent with the concept of optimal frequency introduced by Bergmann and Rainer, can produce a large increase of the superconducting transition temperatureTc. In summary, our results suggest the possibility of reaching high-temperature superconductivity by exploiting soft phonon anomalies restricted in momentum space.
Keyphrases
  • density functional theory
  • high temperature
  • room temperature
  • solar cells