Multistimuli-Responsive and Photocontrolled Supramolecular Luminescent Gels Constructed by Anthracene-Bridged Bis(dibenzo-24-crown-8) with Secondary Ammonium Salt Polymer.

A novel multistimuli-responsive and photcontrolled supramolecular luminescent gel is fabricated from anthracene-bridged bis(dibenzo-24-crown-8) (1) and secondary ammonium salt-functionalized graft polymer (3). X-ray crystallographic analysis reveals that the dibenzo-24-crown-8 (DB24C8) ring is located at the opposite site of 1, which will greatly hinder the mutual intermolecular π-π stacking between anthracene groups. By taking advantage of the controllable binding of 1 with 3, the unique gel-sol transition could occur under different temperatures, pH, and competitive guest bindings. Benefiting from the photo-oxygenation of anthracene, the luminescence behavior of the supramolecular gel could be switched off and on under UV light (365 nm) and heating treatment, which provides a new approach for constructing photocontrolled supramolecular luminescent gel.