Near-Infrared Circularly Polarized Luminescent Physical Unclonable Functions.

Distinguished from traditional physical unclonable functions (PUFs), optical PUFs derive their encoded information from the optical properties of materials, offering distinct advantages, including solution processability, material versatility, and tunable luminescence performance. However, existing research on optical PUFs has predominantly centered on visible photoluminescence, while advanced optical PUFs based on higher-level covert light remain unexplored. In this study, we present optical PUFs based on the utilization of the covert light of near-infrared circularly polarized luminescence (NIR-CPL). This interesting property is achieved by incorporating Yb-doped metal halide perovskite nanocrystals (Yb-PeNCs) possessing NIR emission property into chiral imprinted photonic (CIP) films. By employing a solvent immersion method, we successfully integrated Yb-PeNCs into these CIP films, thereby creating an optically unclonable surface. The resulting NIR-CPL emission adds a layer of advanced security to the optical PUF systems. These findings underscore the potential of solution-processable chiral films to play a pivotal role in advancing the next generation of PUFs.