Optical Anisotropy and Excitons in MoS 2 Interfaces for Sensitive Surface Plasmon Resonance Biosensors.

The use of ultra-thin spacer layers above metal has become a popular approach to the enhancement of optical sensitivity and immobilization efficiency of label-free SPR sensors. At the same time, the giant optical anisotropy inherent to transition metal dichalcogenides may significantly affect characteristics of the studied sensors. Here, we present a systematic study of the optical sensitivity of an SPR biosensor platform with auxiliary layers of MoS 2 . By performing the analysis in a broad spectral range, we reveal the effect of exciton-driven dielectric response of MoS 2 and its anisotropy on the sensitivity characteristics. The excitons are responsible for the decrease in the optimal thickness of MoS 2 . Furthermore, despite the anisotropy being at record height, it affects the sensitivity only slightly, although the effect becomes stronger in the near-infrared spectral range, where it may lead to considerable change in the optimal design of the biosensor.