Login / Signup

Defect Structures of Magnetic Nanoparticles in Smectic A Liquid Crystals.

Vladimíra NovotnáLubor LejčekVĕra HamplováJana Vejpravová
Published in: Molecules (Basel, Switzerland) (2021)
Topological defects in anisotropic fluids like liquid crystals serve as a playground for the research of various effects. In this study, we concentrated on a hybrid system of chiral rod-like molecules doped by magnetic nanoparticles. In textures of the smectic A phase, we observed linear defects and found that clusters of nanoparticles promote nucleation of smectic layer defects just at the phase transition from the isotropic to the smectic A (SmA) phase. In different geometries, we studied and analysed creation of defects which can be explained by attractive elastic forces between nanoparticles in the SmA phase. On cooling the studied hybrid system, clusters grow up to the critical dimension, and the smectic texture is stabilised. The presented effects are theoretically described and explained if we consider the elastic interaction of two point defects and stabilisation of prismatic dislocation loops due to the presence of nanoparticles.
Keyphrases
  • magnetic nanoparticles
  • ionic liquid
  • room temperature
  • magnetic resonance imaging
  • mass spectrometry
  • magnetic resonance
  • highly efficient
  • contrast enhanced
  • walled carbon nanotubes
  • neural network