Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(ii)-Pheox complex.

Nga Phan Thi ThanhMasaya ToneHayato InoueIkuhide FujisawaSeiji Iwasa

Published in: Chemical communications (Cambridge, England) (2019)

This work reports the first efficient enantioselective intramolecular Buchner reaction of diazoacetamides. The Ru(ii)-Pheox catalyst was shown to be highly efficient in this transformation in terms of both the regio- and enantioselectivity (up to 99% ee) giving the desired products in quantitative yield.

Keyphrases

highly efficient
energy transfer
room temperature
quantum dots
emergency department
gold nanoparticles
electronic health record
metal organic framework