Low-Cost and Novel Si-Based Gel for Li-Ion Batteries.

Si-based nanostructure composites have been intensively investigated as anode materials for next-generation lithium-ion batteries because of their ultra-high-energy storage capacity. However, it is still a great challenge to fabricate a perfect structure satisfying all the requirements of good electrical conductivity, robust matrix for buffering large volume expansion, and intact linkage of Si particles upon long-term cycling. Here, we report a novel design of Si-based multicomponent three-dimensional (3D) networks in which the Si core is capped with phytic acid shell layers through a facile high-energy ball-milling method. By mixing the functional Si with graphene oxide and functionalized carbon nanotube, we successfully obtained a homogeneous and conductive rigid silicon-based gel through complexation. Interestingly, this Si-based gel with a fancy 3D cross-linking structure could be writable and printable. In particular, this Si-based gel composite delivers a moderate specific capacity of 2711 mA h g-1 at a current density of 420 mA g-1 and retained a competitive discharge capacity of more than 800.00 mA h g-1 at the current density of 420 mA g-1 after 700 cycles. We provide a new method to fabricate durable Si-based anode material for next-generation high-performance lithium-ion batteries.