Coal fly ash driven zeolites for the adsorptive removal of the ceftazidime drug.

The overall cost and efficiency of an adsorbent material is a major issue in deriving a sorbent into commercial markets. In this study, efforts have been directed to produce adsorption-capable zeolites from the dispensable product of coal power plants, i.e. , coal fly ash (CFA). In addition, coal mining water (CW) was used as a direct hydrothermal solvent. The mine water from China's coal mines was used in this experiment to substitute tap water (TP) for synthesizing zeolite from C-type fly ashes with different crystallization temperatures (45 to 95 °C). Here, CW led to the formation of X-type and A-type zeolites of comparable size. Regarding the proper utilization of waste products, i.e. , coal fly ash and mine water, the study paves a simple yet extremely cost-effective approach to synthesize workable zeolitic materials for adsorption purposes. The detailed characterization justified the use of CW as a better solvent than TP to prepare zeolites based on their better granular size and fewer carbon impurities. The prepared zeolites were later used as an adsorbent for the trace removal of ceftazidime (CAZ), taken as a model pharmaceutical pollutant. The zeolites prepared using CW realised a higher adsorption capacity of 80 mg g -1 during 20 min of agitation time. The pH, concentration, and external salt effects were also studied to achieve maximum removal efficiency. In general, the proposed approach enables the production of affordable yet efficient zeolite-based adsorbent materials without consuming any toxic and expensive reagents for practical application in environmental remediations.