Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(II) centres and 2-nitroimidazolates.

Cheolwon JungSang Beom ChoiJaewoo ParkMinji JungJonghoon Kim Hyunchul Oh Jaheon Kim

Published in: Chemical communications (Cambridge, England) (2023)

Cu(II)-based zeolitic imidazolates (Cu-ZIFs), Cu-ZIF-gis and -rho, formulated as Cu(nIm) 2 (nIm = 2-nitroimidazolate) have highly-flattened tetrahedral coordination geometry. Cu-ZIF-gis has 2.4 Å cylindrical pores that can adsorb H 2 gas, and Cu-ZIF-rho has 19.8 Å cages with a BET surface area of 1320 m 2 g -1 .

Keyphrases

metal organic framework
aqueous solution
room temperature
smooth muscle
highly efficient
carbon dioxide