Large-Scale Continuous and In Situ Photosynthesis of Hydrogen Peroxide by Sulfur-Functionalized Polymer Catalyst for Water Treatment.

Photocatalytic H 2 O 2 generation system based on polymer catalyst receives increasing attention in recent years; however, the insufficient charge separation efficiency and low oxygen adsorption/activation capacity severely limit their potential application. In this study, a sulfur (C=S) functionalized polymer catalyst is reported through a green water-mediated and catalyst-free multi-component reactions (MCRs) route. The sulfur functional group endows the polymer with a suitable energy band and facilitates the separation of photogenerated electron-hole pair. The reported polymer achieves a high H 2 O 2 production efficiency (3132 μmol g -1  h -1 ) in pure water without oxygen aeration. To demonstrate their potential in in situ wastewater treatment, a panel reactor system (20×20 cm) is constructed for large-scale production of H 2 O 2 , which realizes continuous degradation of emerging pollutants including antibiotics and bisphenol A under natural sunlight irradiation condition. The H 2 O 2 utilization efficiency of the photo-self-Fenton system using in situ generated H 2 O 2 is found 7.9 times higher than that of the traditional photo-Fenton system. This study offers new insights in green synthesis and design of functional polymer photocatalyst, and demonstrates the feasibility of panel reactor system for large-scale continuous H 2 O 2 photocatalytic production and water treatment.