Molybdenum tungsten hydrogen oxide doped with phosphorus for enhanced oxygen/hydrogen evolution reactions.

The development of efficient electrocatalysts for hydrogen and oxygen evolution reactions (HER and OER) is pivotal for advancing cleaner and sustainable fuel production technologies. The conventional electrocatalysts have limited stability and higher overpotentials, and there is demand to explore advanced materials and synthesis methods. In this context, a novel bifunctional electrocatalyst has been devised through the phosphidation of tungsten molybdenum oxide (P-Mo 0.69 W 0.31 H 0.98 O 3 ) at relatively low temperatures. This innovative approach aims to enhance the efficiency of HER and OER while minimizing the overpotential values and maintaining higher stability. Specifically, the individual performance of Mo 0.69 W 0.31 H 0.98 O 3 has been significantly boosted by doping it with phosphorus at a low temperature of 300 °C. This doping process results in a unique morphology for the catalyst, leading to a notable improvement in OER/HER performances. P-Mo 0.69 W 0.31 H 0.98 O 3 exhibits a potential of 320 mV at 10 mA cm -2 in a KOH electrolyte, demonstrating both high activity and long-term stability. Additionally, P-Mo 0.69 W 0.31 H 0.98 O 3 exhibits commendable HER performance, requiring only 380 mV at 100 mA cm -2 . This combination of efficient OER and HER performance positions P-Mo 0.69 W 0.31 H 0.98 O 3 as representing a significant advancement in the field of electrocatalysis, additionally addressing the fundamental gap by providing stable and hybrid catalyst for various electrochemical devices. Given its cost-effectiveness and exceptional activity, P-Mo 0.69 W 0.31 H 0.98 O 3 holds significant potential for advancing the field of electrocatalysis and contributing to the development of cleaner and sustainable fuel production methods.