An air-persistent oxyallyl radical cation with simple di(methyl)amino substituents.
Vianney RegnierFlorian MoltonChristian PhilouzeDavid MartinPublished in: Chemical communications (Cambridge, England) (2018)
We report an experimental and theoretical study of the 1,1,3,3-tetrakis-di(methylamino)oxyallyl radical cation. Despite simple substituents with minimal steric hindrance, this radical was found to be stable under an inert atmosphere and persistent for several hours in well-aerated solutions.