Inter- and intramolecular excimer circularly polarised luminescence of planar chiral paracyclophane-pyrene luminophores.

Two types of planar chiral [2,2]paracyclophane-pyrene luminophores (1 and 2) with different binding positions of the fluorescent pyrene units were synthesised. ( R )/( S )-1 with 1-pyrene units exhibited green intermolecular excimer circularly polarised luminescence (CPL) at 530 nm in the KBr-pellet, but exhibited no CPL signal in dilute CHCl 3 solution. In contrast, ( R )/( S )-2 with 2-pyrene units exhibited a blue intramolecular excimer CPL at 450 nm in CHCl 3 solution. This is the first example of using the binding position of pyrene and the external environment to tune the type (inter- or intramolecular) and chiroptical sign of excimer CPL.